| 21‑Oct‑2012 | Valencia | Hard | R32 | 58 | 7 | Malisse d. (2)Jo Wilfried Tsonga [FRA] | 3-1 RET | | 2.50 | 30.0% | 0.0% | 40.0% | 75.0% | 83.3% | 0/0 | 0:24 |
| 8‑Jun‑2009 | Queen's Club | Grass | R64 | 172 | 103 | (Q)Malisse d. Pablo Andujar [ESP] | 5-0 RET | | 2.20 | 18.2% | 0.0% | 72.7% | 87.5% | 33.3% | 0/0 | 0:23 |
| 3‑Oct‑2005 | Mons CH | Carpet | QF | 42 | 72 | (2)Malisse d. (7)Andy Murray [GBR] | 7-5 1-0 RET | | | | | | | | | |
| 24‑May‑2004 | Roland Garros | Clay | R64 | 54 | 161 | Malisse d. (Q)Daniel Elsner [GER] | 6-3 4-0 RET | | 1.63 | 14.6% | 2.1% | 56.3% | 74.1% | 47.6% | 2/3 | 0:54 |
| 21‑Apr‑2003 | Barcelona | Clay | R64 | 28 | 94 | (14)Malisse d. Hicham Arazi [MAR] | 7-5 RET | | 1.43 | 11.8% | 0.0% | 58.8% | 80.0% | 64.3% | 1/1 | 0:40 |
| 7‑Jan‑2002 | Sydney | Hard | R32 | 31 | 24 | Malisse d. Hicham Arazi [MAR] | 6-3 RET | | 1.66 | 7.7% | 7.7% | 50.0% | 84.6% | 61.5% | 3/3 | 0:38 |
| 8‑Oct‑2001 | Lyon | Carpet | QF | 41 | 53 | Malisse d. Jonas Bjorkman [SWE] | 6-1 4-1 RET | | 2.05 | 20.9% | 7.0% | 58.1% | 88.0% | 50.0% | 5/5 | 1:00 |
| 27‑Aug‑2001 | US Open | Hard | R128 | 43 | 262 | Malisse d. Kenneth Carlsen [DEN] | 6-1 4-6 3-6 2-1 RET | | 1.11 | 12.8% | 7.0% | 61.6% | 81.1% | 39.4% | 4/8 | 2:03 |
| 28‑May‑2001 | Roland Garros | Clay | R64 | 63 | 118 | Malisse d. (Q)Kristian Pless [DEN] | 4-0 RET | | 1.83 | 16.7% | 0.0% | 41.7% | 80.0% | 57.1% | 0/0 | 0:15 |
| 26‑Feb‑2001 | San Jose | Hard | QF | 115 | 21 | (Q)Malisse d. (4)Tommy Haas [GER] | 5-7 6-3 5-1 RET | | 1.38 | 11.3% | 2.5% | 57.5% | 80.4% | 50.0% | 1/3 | 1:47 |
| 14‑Aug‑2000 | Indianapolis | Hard | R32 | 172 | 19 | (Q)Malisse d. (8)Marcelo Rios [CHI] | 6-4 RET | | 0.97 | 2.7% | 13.5% | 51.4% | 68.4% | 50.0% | 4/5 | 0:40 |
| 2‑Aug‑1997 | Belgium Masters 3 | Clay | R32 | 1044 | 658 | Malisse d. (6)Arnaud Fontaine [BEL] | 6-2 RET | | | | | | | | | |