| 21‑Nov‑2010 | Tour Finals | Hard | RR | 3 | 1 | Rafael Nadal [ESP] d. Djokovic | 7-5 6-2 | (ch) | 0.76 | 11.5% | 1.6% | 63.9% | 64.1% | 45.5% | 4/8 | 1:52 |
| 30‑Sep‑2013 | Beijing | Hard | F | 1 | 2 | (1)Djokovic d. (2)Rafael Nadal [ESP] | 6-3 6-4 | (ch) | 2.81 | 10.9% | 2.2% | 71.7% | 90.9% | 76.9% | 0/0 | 1:27 |
| 4‑Nov‑2013 | Tour Finals | Hard | F | 2 | 1 | (2)Djokovic d. (1)Rafael Nadal [ESP] | 6-3 6-4 | (ch) | 1.43 | 10.3% | 0.0% | 65.5% | 68.4% | 70.0% | 2/3 | 1:36 |
| 5‑Aug‑2013 | Canada Masters | Hard | SF | 1 | 4 | (4)Rafael Nadal [ESP] d. (1)Djokovic | 6-4 3-6 7-6(2) | (ch) | 0.95 | 8.2% | 7.1% | 64.3% | 71.4% | 54.3% | 3/5 | 2:29 |
| 26‑Aug‑2013 | US Open | Hard | F | 1 | 2 | (2)Rafael Nadal [ESP] d. (1)Djokovic | 6-2 3-6 6-4 6-1 | (ch) | 0.84 | 5.9% | 2.0% | 67.6% | 58.0% | 48.5% | 5/11 | 3:21 |
| 29‑Aug‑2011 | US Open | Hard | F | 1 | 2 | (1)Djokovic d. (2)Rafael Nadal [ESP] | 6-2 6-4 6-7(3) 6-1 | (ch) | 1.22 | 5.5% | 0.8% | 66.1% | 65.5% | 44.2% | 8/14 | 4:10 |
| 16‑Jan‑2012 | Australian Open | Hard | F | 1 | 2 | (1)Djokovic d. (2)Rafael Nadal [ESP] | 5-7 6-4 6-2 6-7(5) 7-5 | (ch) | 1.21 | 5.4% | 1.2% | 59.0% | 68.4% | 63.2% | 2/6 | 5:53 |
| 10‑Mar‑2011 | Indian Wells Masters | Hard | F | 3 | 1 | (3)Djokovic d. (1)Rafael Nadal [ESP] | 4-6 6-3 6-2 | (ch) | 1.12 | 4.5% | 4.5% | 61.8% | 74.5% | 52.9% | 6/9 | 2:26 |
| 30‑Aug‑2010 | US Open | Hard | F | 3 | 1 | (1)Rafael Nadal [ESP] d. (3)Djokovic | 6-4 5-7 6-4 6-2 | (ch) | 0.77 | 3.5% | 2.8% | 65.7% | 64.9% | 44.9% | 20/25 | 3:43 |
| 23‑Mar‑2011 | Miami Masters | Hard | F | 2 | 1 | (2)Djokovic d. (1)Rafael Nadal [ESP] | 4-6 6-3 7-6(4) | (ch) | 1.27 | 3.2% | 0.0% | 56.8% | 66.7% | 70.7% | 2/4 | 3:22 |
