| 13‑Jan‑2025 | Australian Open | Hard | R128 | 62 | 6 | (6)Casper Ruud [NOR] d. Munar | 6-3 1-6 7-5 2-6 6-1 | (ch) | 0.89 | 7.2% | 2.2% | 65.2% | 73.3% | 37.5% | 7/12 | 3:21 |
| 14‑Oct‑2024 | Antwerp | Hard | R32 | 65 | 33 | (5)Jiri Lehecka [CZE] d. Munar | 6-1 6-4 | (ch) | 0.60 | 1.7% | 6.7% | 63.3% | 57.9% | 36.4% | 5/9 | 1:25 |
| 15‑Jul‑2024 | Hamburg | Clay | R32 | 59 | 28 | (5)Arthur Fils [FRA] d. Munar | 5-7 6-3 6-1 | | 0.75 | 2.5% | 3.8% | 54.4% | 62.8% | 50.0% | 5/10 | 2:11 |
| 27‑May‑2024 | Roland Garros | Clay | R64 | 64 | 11 | (11)Alex De Minaur [AUS] d. Munar | 7-5 6-1 6-4 | | 0.68 | 1.0% | 12.1% | 60.6% | 56.7% | 46.2% | 6/13 | |
| 22‑Apr‑2024 | Madrid Masters | Clay | R64 | 73 | 24 | (23)Jan Lennard Struff [GER] d. Munar | 6-1 7-5 | | 0.54 | 1.4% | 4.3% | 62.3% | 53.5% | 46.2% | 6/10 | 1:25 |
| 8‑Apr‑2024 | Monte Carlo Masters | Clay | R64 | 72 | 41 | Roman Safiullin [RUS] d. (Q)Munar | 7-5 6-1 | | 0.71 | 1.6% | 4.9% | 70.5% | 60.5% | 33.3% | 6/10 | 1:36 |
