| 16‑Jan‑2012 | Australian Open | Hard | F | 1 | 2 | (1)Djokovic d. (2)Rafael Nadal [ESP] | 5-7 6-4 6-2 6-7(5) 7-5 | (ch) | 1.21 | 5.4% | 1.2% | 59.0% | 68.4% | 63.2% | 2/6 | 5:53 |
| 2‑Jul‑2018 | Wimbledon | Grass | SF | 21 | 1 | (12)Djokovic d. (2)Rafael Nadal [ESP] | 6-4 3-6 7-6(9) 3-6 10-8 | (ch) | 1.12 | 13.1% | 2.3% | 71.0% | 76.0% | 47.1% | 7/11 | 5:15 |
| 14‑Jan‑2013 | Australian Open | Hard | R16 | 1 | 17 | (1)Djokovic d. (15)Stan Wawrinka [SUI] | 1-6 7-5 6-4 6-7(5) 12-10 | (ch) | 1.10 | 3.6% | 2.6% | 66.2% | 71.3% | 54.5% | 11/18 | 5:02 |
| 25‑Jun‑2007 | Wimbledon | Grass | QF | 5 | 16 | (4)Djokovic d. (10)Marcos Baghdatis [CYP] | 7-6(4) 7-6(9) 6-7(3) 4-6 7-5 | | 1.13 | 6.4% | 2.1% | 69.7% | 72.5% | 52.6% | 3/8 | 5:00 |
| 1‑Jul‑2019 | Wimbledon | Grass | F | 1 | 3 | (1)Djokovic d. (2)Roger Federer [SUI] | 7-6(5) 1-6 7-6(4) 4-6 13-12(3) | (ch) | 0.87 | 4.6% | 4.1% | 62.1% | 74.3% | 47.0% | 6/13 | 4:57 |
| 4‑Mar‑2016 | Davis Cup WG R1: SRB vs KAZ | Hard | RR | 1 | 79 | Djokovic d. Mikhail Kukushkin [KAZ] | 6-7(6) 7-6(3) 4-6 6-3 6-2 | | 1.17 | 11.0% | 6.9% | 67.6% | 76.1% | 41.1% | 3/8 | 4:57 |
| 27‑Aug‑2012 | US Open | Hard | F | 2 | 4 | (3)Andy Murray [GBR] d. (2)Djokovic | 7-6(10) 7-5 2-6 3-6 6-2 | (ch) | 0.95 | 4.2% | 3.0% | 62.4% | 63.1% | 41.9% | 8/15 | 4:54 |
| 16‑Jan‑2012 | Australian Open | Hard | SF | 1 | 4 | (1)Djokovic d. (4)Andy Murray [GBR] | 6-3 3-6 6-7(4) 6-1 7-5 | (ch) | 1.16 | 6.4% | 3.5% | 60.8% | 66.3% | 44.8% | 17/24 | 4:50 |
| 16‑Jan‑2017 | Australian Open | Hard | R64 | 2 | 117 | Denis Istomin [UZB] d. (2)Djokovic | 7-6(8) 5-7 2-6 7-6(5) 6-4 | (ch) | 1.07 | 7.6% | 4.9% | 57.8% | 72.0% | 55.1% | 10/14 | 4:48 |
| 3‑Jul‑2023 | Wimbledon | Grass | F | 2 | 1 | (1)Carlos Alcaraz [ESP] d. (2)Djokovic | 1-6 7-6(6) 6-1 3-6 6-4 | (ch) | 0.93 | 1.1% | 1.6% | 64.1% | 61.9% | 56.1% | 14/19 | 4:43 |
| 24‑Jun‑2013 | Wimbledon | Grass | SF | 1 | 8 | (1)Djokovic d. (8)Juan Martin Del Potro [ARG] | 7-5 4-6 7-6(2) 6-7(6) 6-3 | (ch) | 1.15 | 12.4% | 1.1% | 69.5% | 82.9% | 38.9% | 5/7 | 4:43 |
| 27‑Aug‑2007 | US Open | Hard | R64 | 3 | 35 | (3)Djokovic d. Radek Stepanek [CZE] | 6-7(4) 7-6(5) 5-7 7-5 7-6(2) | | 1.16 | 10.3% | 2.3% | 55.4% | 79.4% | 62.8% | 4/7 | 4:41 |
| 27‑May‑2013 | Roland Garros | Clay | SF | 1 | 4 | (3)Rafael Nadal [ESP] d. (1)Djokovic | 6-4 3-6 6-1 6-7(3) 9-7 | (ch) | 0.82 | 2.9% | 1.1% | 67.4% | 64.4% | 52.6% | 8/16 | 4:37 |
| 18‑Jan‑2016 | Australian Open | Hard | R16 | 1 | 15 | (1)Djokovic d. (14)Gilles Simon [FRA] | 6-3 6-7 6-4 4-6 6-3 | (ch) | 1.19 | 5.1% | 0.6% | 62.1% | 70.0% | 55.2% | 14/18 | 4:32 |
