| 19‑Mar‑2025 | Miami | Hard | R64 | 54 | 7 | Mensik d. (6)Jack Draper [GBR] | 7-6(2) 7-6(3) | | 1.35 | 27.6% | 0.0% | 65.8% | 86.0% | 53.8% | 1/2 | 1:54 |
| 3‑Feb‑2025 | Rotterdam | Hard | R16 | 47 | 8 | (3)Alex De Minaur [AUS] d. Mensik | 6-4 6-4 | (ch) | 0.46 | 15.8% | 6.6% | 56.6% | 79.1% | 30.3% | 6/8 | 1:28 |
| 13‑Jan‑2025 | Australian Open | Hard | R64 | 48 | 6 | Mensik d. (6)Casper Ruud [NOR] | 6-2 3-6 6-1 6-4 | (ch) | 1.37 | 20.4% | 0.9% | 60.2% | 70.8% | 65.1% | 7/8 | 2:44 |
| 21‑Oct‑2024 | Vienna | Hard | QF | 51 | 10 | (2)Alex De Minaur [AUS] d. (Q)Mensik | 6-7(2) 6-3 6-4 | | 0.91 | 14.9% | 2.0% | 63.4% | 76.6% | 45.9% | 3/5 | 2:34 |
| 2‑Oct‑2024 | Shanghai Masters | Hard | QF | 65 | 4 | (4)Novak Djokovic [SRB] d. Mensik | 6-7(4) 6-1 6-4 | (ch) | 0.68 | 15.6% | 5.5% | 59.6% | 78.5% | 34.1% | 5/9 | 2:19 |
| 2‑Oct‑2024 | Shanghai Masters | Hard | R16 | 65 | 10 | Mensik d. (9)Grigor Dimitrov [BUL] | 6-3 3-6 6-4 | | 1.01 | 11.2% | 6.7% | 60.7% | 77.8% | 40.0% | 2/4 | 2:03 |
| 2‑Oct‑2024 | Shanghai Masters | Hard | R64 | 65 | 6 | Mensik d. (6)Andrey Rublev [RUS] | 6-7(7) 6-4 6-3 | | 1.13 | 10.3% | 1.9% | 54.2% | 70.7% | 53.1% | 8/12 | 2:30 |
| 22‑Apr‑2024 | Madrid Masters | Clay | R64 | 74 | 10 | Mensik d. (9)Grigor Dimitrov [BUL] | 6-2 6-7(4) 6-3 | | 0.96 | 12.7% | 4.0% | 58.7% | 68.9% | 53.8% | 7/8 | 2:34 |
| 19‑Feb‑2024 | Doha | Hard | QF | 116 | 5 | Mensik d. (1)Andrey Rublev [RUS] | 6-4 7-6(6) | (ch) | 0.93 | 12.7% | 0.0% | 65.8% | 80.8% | 48.1% | 6/6 | 1:36 |
| 15‑Jan‑2024 | Australian Open | Hard | R64 | 142 | 9 | (9)Hubert Hurkacz [POL] d. (Q)Mensik | 6-7(9) 6-1 5-7 6-1 6-3 | (ch) | 0.63 | 11.4% | 6.0% | 60.5% | 75.2% | 36.4% | 14/21 | 3:25 |
| 28‑Aug‑2023 | US Open | Hard | R32 | 206 | 9 | (9)Taylor Fritz [USA] d. (Q)Mensik | 6-1 6-2 6-0 | | 0.37 | 1.8% | 5.3% | 56.1% | 46.9% | 28.0% | 2/9 | 1:30 |