| 1‑Oct‑2007 | Metz | Hard | R16 | 42 | 14 | (2)Guillermo Canas [ARG] d. (Q)Melzer | 7-6(3) 7-6(6) | | 0.88 | 6.7% | 1.1% | 77.8% | 64.3% | 35.0% | 3/5 | 2:18 |
| 1‑Oct‑2007 | Metz | Hard | R32 | 42 | 192 | (Q)Melzer d. (Q)David Guez [FRA] | 7-5 6-7(2) 6-2 | | 1.19 | 12.6% | 0.0% | 63.1% | 69.2% | 50.0% | 6/10 | 2:46 |
| 1‑Oct‑2007 | Metz Q | Hard | Q3 | 42 | 945 | (1)Melzer d. Roman Valent [SUI] | 6-2 2-6 6-2 | | | | | | | | | |
| 1‑Oct‑2007 | Metz Q | Hard | Q2 | 42 | 318 | (1)Melzer d. George Bastl [SUI] | 6-2 6-4 | | | | | | | | | |
| 2‑Oct‑2006 | Metz | Hard | F | 48 | 22 | (3)Novak Djokovic [SRB] d. Melzer | 4-6 6-3 6-2 | (ch) | 0.81 | 2.2% | 5.6% | 50.0% | 68.9% | 44.4% | 7/11 | 1:51 |
| 2‑Oct‑2006 | Metz | Hard | SF | 48 | 70 | Melzer d. (WC)Marc Gicquel [FRA] | 7-6(3) 6-3 | | 1.12 | 8.8% | 5.0% | 65.0% | 71.2% | 42.9% | 5/7 | 1:24 |
| 2‑Oct‑2006 | Metz | Hard | QF | 48 | 56 | Melzer d. Mardy Fish [USA] | 1-6 7-5 7-5 | | 1.02 | 5.2% | 4.2% | 58.3% | 71.4% | 45.0% | 5/9 | 2:03 |
| 2‑Oct‑2006 | Metz | Hard | R16 | 48 | 63 | Melzer d. Marat Safin [RUS] | 4-6 6-2 7-6(5) | | 1.01 | 3.7% | 2.8% | 64.2% | 72.9% | 56.4% | 10/11 | 2:04 |
| 2‑Oct‑2006 | Metz | Hard | R32 | 48 | 82 | Melzer d. Albert Montanes [ESP] | 7-5 6-2 | | 1.45 | 14.5% | 3.2% | 59.7% | 75.7% | 48.0% | 4/6 | 1:08 |
| 3‑Oct‑2005 | Metz | Hard | R32 | 49 | 80 | Fabrice Santoro [FRA] d. Melzer | 4-6 6-3 6-2 | | 0.70 | 6.2% | 1.2% | 60.5% | 67.3% | 37.5% | 7/12 | 1:45 |
| 29‑Sep‑2003 | Metz | Hard | R32 | 84 | 18 | (1)Tommy Robredo [ESP] d. Melzer | 6-2 7-6(5) | | 0.64 | 4.9% | 1.2% | 65.9% | 61.1% | 46.4% | 9/12 | 1:25 |
