| 15‑Oct‑2007 | Madrid Masters | Hard | R64 | 46 | 26 | Nicolas Almagro [ESP] d. Santoro | 6-4 6-4 | | 0.70 | 6.8% | 3.4% | 50.8% | 63.3% | 55.2% | 3/6 | 1:19 |
| 14‑Oct‑2002 | Madrid Masters | Hard | SF | 50 | 9 | (11)Jiri Novak [CZE] d. (Q)Santoro | 6-2 6-4 | (ch) | 0.64 | 5.4% | 3.6% | 60.7% | 58.8% | 36.4% | 4/8 | 1:07 |
| 14‑Oct‑2002 | Madrid Masters | Hard | QF | 50 | 7 | (Q)Santoro d. (12)Roger Federer [SUI] | 7-5 6-3 | | 1.09 | 1.4% | 2.8% | 62.0% | 72.7% | 51.9% | 5/6 | 1:18 |
| 14‑Oct‑2002 | Madrid Masters | Hard | R16 | 50 | 18 | (Q)Santoro d. David Nalbandian [ARG] | 6-0 6-2 | | 2.35 | 5.3% | 2.6% | 44.7% | 88.2% | 66.7% | 0/0 | 1:03 |
| 14‑Oct‑2002 | Madrid Masters | Hard | R32 | 50 | 3 | (Q)Santoro d. (1)Tommy Haas [GER] | 7-6(7) 4-1 RET | | 1.83 | 15.4% | 3.8% | 50.0% | 92.3% | 65.4% | 4/4 | 1:11 |
| 14‑Oct‑2002 | Madrid Masters | Hard | R64 | 50 | 51 | (Q)Santoro d. (Q)Julien Boutter [FRA] | 6-3 7-6(4) | | 1.32 | 1.6% | 3.2% | 60.3% | 76.3% | 68.0% | 0/1 | 1:31 |