| 29‑Jan‑2024 | Montpellier | Hard | R32 | 70 | 76 | Flavio Cobolli [ITA] d. (8)Monfils | 6-7(8) 6-3 6-0 | | 0.80 | 5.8% | 6.8% | 50.5% | 61.5% | 43.1% | 9/16 | 2:40 |
| 31‑May‑2021 | Roland Garros | Clay | R64 | 15 | 105 | Mikael Ymer [SWE] d. (14)Monfils | 6-0 2-6 6-4 6-3 | (ch) | 0.82 | 4.5% | 2.7% | 57.3% | 60.3% | 40.4% | 3/10 | 2:24 |
| 6‑May‑2019 | Madrid Masters | Clay | R16 | 18 | 3 | (4)Roger Federer [SUI] d. (15)Monfils | 6-0 4-6 7-6(3) | (ch) | 0.71 | 6.7% | 6.7% | 57.1% | 68.3% | 40.0% | 8/13 | 2:00 |
| 8‑May‑2017 | Madrid Masters | Clay | R64 | 16 | 32 | Gilles Simon [FRA] d. (15)Monfils | 0-6 6-0 7-6(0) | (ch) | 0.88 | 4.2% | 5.6% | 68.1% | 61.2% | 34.8% | 0/4 | 2:01 |
| 27‑Jun‑2016 | Wimbledon | Grass | R128 | 16 | 34 | Jeremy Chardy [FRA] d. (17)Monfils | 6-7(4) 6-0 4-6 6-1 6-2 | | 0.69 | 13.7% | 5.0% | 65.5% | 64.8% | 41.7% | 6/13 | 2:36 |
| 11‑Apr‑2016 | Monte Carlo Masters | Clay | F | 16 | 5 | (5)Rafael Nadal [ESP] d. (13)Monfils | 7-5 5-7 6-0 | (ch) | 0.81 | 4.1% | 7.1% | 64.3% | 52.4% | 40.0% | 13/21 | 2:46 |
| 26‑May‑2014 | Roland Garros | Clay | QF | 28 | 8 | (7)Andy Murray [GBR] d. (23)Monfils | 6-4 6-1 4-6 1-6 6-0 | | 0.81 | 2.9% | 3.6% | 75.5% | 60.0% | 41.2% | 11/18 | 3:15 |
| 26‑May‑2014 | Roland Garros | Clay | R32 | 28 | 15 | (23)Monfils d. (14)Fabio Fognini [ITA] | 5-7 6-2 6-4 0-6 6-2 | | 1.09 | 3.4% | 3.4% | 77.9% | 54.3% | 51.5% | 15/24 | 3:24 |
| 22‑Jul‑2013 | Umag | Clay | SF | 56 | 19 | (3)Fabio Fognini [ITA] d. Monfils | 6-0 3-6 7-6(3) | | 0.95 | 2.4% | 4.9% | 68.3% | 57.1% | 42.3% | 10/16 | 1:55 |
| 19‑May‑2013 | Nice | Clay | F | 109 | 82 | Albert Montanes [ESP] d. (WC)Monfils | 6-0 7-6(3) | | 0.66 | 3.8% | 0.0% | 77.4% | 53.7% | 50.0% | 0/4 | 1:14 |
| 29‑Apr‑2013 | Munich | Clay | R16 | 103 | 69 | Daniel Brands [GER] d. (WC)Monfils | 6-3 3-6 6-0 | | 0.70 | 7.2% | 2.9% | 65.2% | 68.9% | 45.8% | 4/8 | 1:10 |
| 8‑Apr‑2013 | Houston | Clay | R16 | 103 | 12 | (1)Nicolas Almagro [ESP] d. Monfils | 2-6 6-0 6-3 | | 0.71 | 4.9% | 9.8% | 65.6% | 60.0% | 42.9% | 3/7 | 1:26 |
| 14‑Jan‑2013 | Australian Open | Hard | R64 | 86 | 61 | Monfils d. Yen Hsun Lu [TPE] | 7-6(5) 4-6 0-6 6-1 8-6 | | 0.93 | 18.2% | 13.9% | 58.8% | 76.3% | 41.2% | 5/10 | 3:37 |
| 18‑Jul‑2011 | Hamburg | Clay | QF | 7 | 18 | (5)Gilles Simon [FRA] d. (1)Monfils | 6-4 3-6 6-0 | | 0.84 | 2.4% | 3.7% | 64.6% | 60.4% | 41.4% | 2/7 | 2:05 |
| 22‑Sep‑2008 | Bangkok | Hard | SF | 30 | 20 | (2)Jo Wilfried Tsonga [FRA] d. (4)Monfils | 6-0 6-3 | | 0.49 | 12.5% | 2.5% | 60.0% | 66.7% | 31.3% | 2/6 | 1:00 |
| 17‑Jun‑2007 | s Hertogenbosch | Grass | R32 | 73 | 13 | (2)Ivan Ljubicic [CRO] d. Monfils | 3-6 6-3 6-0 | | 0.83 | 26.2% | 9.2% | 44.6% | 79.3% | 50.0% | 5/9 | 1:25 |
| 20‑May‑2007 | Poertschach | Clay | F | 75 | 47 | Juan Monaco [ARG] d. (WC)Monfils | 7-6(3) 6-0 | | 0.51 | 3.3% | 10.0% | 46.7% | 53.6% | 46.9% | 6/10 | 1:21 |
| 15‑Apr‑2007 | Monte Carlo Masters | Clay | R64 | 42 | 25 | Radek Stepanek [CZE] d. Monfils | 6-0 2-0 RET | | 0.22 | 8.0% | 8.0% | 48.0% | 33.3% | 23.1% | 0/4 | 0:43 |
| 15‑Jan‑2007 | Australian Open | Hard | R32 | 59 | 17 | (18)Richard Gasquet [FRA] d. Monfils | 6-0 4-6 7-5 6-3 | | 0.63 | 8.6% | 2.9% | 64.8% | 63.2% | 51.4% | 3/9 | 2:26 |
| 6‑Mar‑2006 | Indian Wells Masters | Hard | R64 | 29 | 139 | (27)Monfils d. (Q)Jeff Morrison [USA] | 6-3 0-6 6-3 | | 0.92 | 5.7% | 2.9% | 64.3% | 73.3% | 36.0% | 2/5 | 1:26 |
| 3‑Oct‑2005 | Metz | Hard | F | 45 | 16 | (3)Ivan Ljubicic [CRO] d. (6)Monfils | 7-6(7) 6-0 | | 0.58 | 8.6% | 3.4% | 44.8% | 69.2% | 43.8% | 3/7 | 1:29 |
| 23‑May‑2005 | Roland Garros | Clay | R128 | 79 | 10 | (9)Guillermo Canas [ARG] d. (WC)Monfils | 6-3 6-1 6-0 | | 0.53 | 2.6% | 5.3% | 44.7% | 47.1% | 31.0% | 4/13 | 1:41 |
