| 19‑Mar‑2025 | Miami | Hard | QF | 54 | 18 | Mensik d. (17)Arthur Fils [FRA] | 7-6(5) 6-1 | | 1.59 | 24.5% | 3.8% | 66.0% | 85.7% | 50.0% | 2/3 | 1:15 |
| 19‑Mar‑2025 | Miami | Hard | R128 | 54 | 50 | Mensik d. Roberto Bautista Agut [ESP] | 6-4 3-6 6-1 | | 1.09 | 26.7% | 3.5% | 66.3% | 84.2% | 31.0% | 7/8 | 1:53 |
| 13‑Jan‑2025 | Australian Open | Hard | R64 | 48 | 6 | Mensik d. (6)Casper Ruud [NOR] | 6-2 3-6 6-1 6-4 | (ch) | 1.37 | 20.4% | 0.9% | 60.2% | 70.8% | 65.1% | 7/8 | 2:44 |
| 13‑Jan‑2025 | Australian Open | Hard | R128 | 48 | 206 | Mensik d. (Q)Nikoloz Basilashvili [GEO] | 6-1 6-7(3) 6-3 6-3 | | 1.27 | 24.8% | 6.4% | 54.4% | 82.4% | 50.9% | 11/12 | 2:33 |
| 2‑Oct‑2024 | Shanghai Masters | Hard | R32 | 65 | 58 | Mensik d. Alexander Shevchenko [KAZ] | 6-1 6-7(5) 6-2 | | 1.63 | 11.1% | 1.2% | 58.0% | 83.0% | 58.8% | 1/2 | 1:56 |
| 2‑Oct‑2024 | Shanghai Masters | Hard | R128 | 65 | 45 | Mensik d. Pedro Martinez [ESP] | 6-1 5-7 6-4 | | 1.42 | 17.3% | 4.9% | 65.4% | 77.4% | 57.1% | 2/4 | 1:58 |
| 22‑Jul‑2024 | Umag | Clay | QF | 81 | 159 | Mensik d. (LL)Chun Hsin Tseng [TPE] | 6-0 6-4 | | 1.36 | 3.6% | 5.4% | 62.5% | 74.3% | 42.9% | 3/4 | 1:20 |
| 24‑Jun‑2024 | Mallorca | Grass | R32 | 85 | 42 | Mensik d. (8)Christopher Eubanks [USA] | 6-3 3-6 6-1 | | 1.52 | 17.6% | 1.5% | 66.2% | 84.4% | 60.9% | 3/4 | 1:30 |
| 3‑Feb‑2024 | Davis Cup QLS R1: CZE vs ISR | Hard | RR | 127 | 415 | Mensik d. Yshai Oliel [ISR] | 6-1 7-6(4) | | 1.69 | 15.9% | 4.8% | 58.7% | 86.5% | 61.5% | 3/3 | 1:34 |