| 26‑Sep‑2024 | Beijing | Hard | R32 | 6 | 201 | (4)Rublev d. (PR)Pablo Carreno Busta [ESP] | 6-0 4-6 6-4 | (ch) | 1.27 | 16.0% | 1.3% | 57.3% | 76.7% | 53.1% | 4/6 | 1:49 |
| 15‑Jan‑2024 | Australian Open | Hard | R16 | 5 | 10 | (5)Rublev d. (10)Alex De Minaur [AUS] | 6-4 6-7(5) 6-7(4) 6-3 6-0 | (ch) | 1.13 | 3.3% | 3.3% | 59.4% | 67.3% | 54.8% | 13/16 | 4:14 |
| 2‑Oct‑2023 | Shanghai Masters | Hard | R32 | 7 | 23 | (5)Rublev d. (31)Adrian Mannarino [FRA] | 6-3 6-0 | (ch) | 1.79 | 11.8% | 0.0% | 66.7% | 79.4% | 52.9% | 2/2 | 1:02 |
| 17‑Jul‑2023 | Bastad | Clay | F | 7 | 4 | (2)Rublev d. (1)Casper Ruud [NOR] | 7-6(3) 6-0 | (ch) | 1.72 | 10.0% | 1.7% | 73.3% | 81.8% | 50.0% | 2/3 | 1:31 |
| 29‑May‑2023 | Roland Garros | Clay | R32 | 7 | 48 | Lorenzo Sonego [ITA] d. (7)Rublev | 5-7 0-6 6-3 7-6(5) 6-3 | | 1.11 | 6.7% | 3.0% | 54.1% | 75.3% | 58.1% | 5/9 | 3:43 |
| 29‑Aug‑2022 | US Open | Hard | R64 | 11 | 81 | (9)Rublev d. Soon Woo Kwon [KOR] | 6-3 6-0 6-4 | | 1.39 | 14.3% | 6.0% | 56.0% | 83.0% | 43.2% | 1/2 | 1:43 |
| 18‑Apr‑2022 | Belgrade | Clay | F | 8 | 1 | (2)Rublev d. (1)Novak Djokovic [SRB] | 6-2 6-7(4) 6-0 | (ch) | 1.34 | 6.2% | 4.1% | 57.7% | 73.2% | 51.2% | 8/9 | 2:27 |
| 21‑Feb‑2022 | Dubai | Hard | R16 | 7 | 60 | (2)Rublev d. Soon Woo Kwon [KOR] | 4-6 6-0 6-3 | | 1.57 | 21.4% | 2.9% | 58.6% | 92.7% | 48.3% | 2/3 | 1:42 |
| 17‑Jan‑2022 | Australian Open | Hard | R64 | 6 | 93 | (5)Rublev d. Ricardas Berankis [LTU] | 6-4 6-2 6-0 | | 1.62 | 16.3% | 3.8% | 50.0% | 85.0% | 52.5% | 4/4 | 1:47 |
| 4‑Dec‑2021 | Davis Cup Finals SF: RTF vs GER | Hard | RR | 5 | 54 | Rublev d. Dominik Koepfer [GER] | 6-4 6-0 | | 2.10 | 20.9% | 4.7% | 74.4% | 84.4% | 54.5% | 0/0 | 0:48 |
| 31‑Aug‑2020 | US Open | Hard | R32 | 14 | 100 | (10)Rublev d. Salvatore Caruso [ITA] | 6-0 6-4 6-0 | | 2.00 | 28.3% | 5.0% | 63.3% | 86.8% | 40.9% | 1/2 | 1:24 |
| 24‑Feb‑2020 | Dubai | Hard | R16 | 14 | 33 | (6)Rublev d. Filip Krajinovic [SRB] | 7-6(3) 6-0 | | 1.45 | 21.4% | 3.6% | 55.4% | 71.0% | 52.0% | 1/4 | 1:40 |
| 13‑Jan‑2020 | Adelaide | Hard | F | 18 | 91 | (3)Rublev d. (Q)Lloyd Harris [RSA] | 6-3 6-0 | (ch) | 1.87 | 8.2% | 2.0% | 55.1% | 81.5% | 59.1% | 4/4 | 0:56 |
| 14‑Oct‑2019 | Moscow | Hard | F | 31 | 44 | (6)Rublev d. (7)Adrian Mannarino [FRA] | 6-4 6-0 | (ch) | 2.01 | 15.2% | 6.5% | 69.6% | 84.4% | 50.0% | 1/1 | 1:02 |
| 7‑Oct‑2019 | Shanghai Masters | Hard | R32 | 33 | 58 | Rublev d. (SE)John Millman [AUS] | 6-2 6-0 | | 1.88 | 16.3% | 7.0% | 67.4% | 75.9% | 57.1% | 0/0 | 1:04 |
| 16‑Sep‑2019 | St. Petersburg | Hard | R32 | 38 | 135 | (5)Rublev d. (Q)Ilya Ivashka [BLR] | 4-6 6-0 6-4 | | 1.48 | 4.1% | 1.4% | 50.0% | 75.7% | 59.5% | 7/9 | 1:47 |
| 22‑Oct‑2018 | Vienna | Hard | R32 | 76 | 62 | (LL)Rublev d. (Q)Denis Kudla [USA] | 7-6(3) 6-0 | | 2.11 | 23.6% | 0.0% | 58.2% | 90.6% | 65.2% | 5/5 | 1:01 |
| 1‑Oct‑2018 | Beijing | Hard | R32 | 68 | 43 | Rublev d. (SE)Joao Sousa [POR] | 6-0 6-4 | | 1.62 | 5.6% | 0.0% | 51.9% | 75.0% | 61.5% | 1/1 | 1:06 |
| 19‑Jun‑2017 | Halle | Grass | R16 | 106 | 88 | (WC)Rublev d. (Q)Mikhail Youzhny [RUS] | 6-0 3-6 6-3 | | 1.65 | 15.0% | 1.7% | 60.0% | 80.6% | 66.7% | 0/1 | 1:28 |
| 29‑May‑2017 | Roland Garros | Clay | R128 | 118 | 41 | Diego Schwartzman [ARG] d. (LL)Rublev | 0-6 6-4 6-2 6-7(3) 9-7 | | 1.01 | 2.5% | 4.3% | 51.5% | 65.5% | 55.7% | 10/18 | 3:30 |
