| 4‑Nov‑2024 | Metz | Hard | R16 | 127 | 84 | (Q)Quentin Halys [FRA] d. (LL)Herbert | 6-1 4-6 6-4 | | 0.98 | 11.8% | 3.2% | 68.8% | 70.3% | 48.3% | 2/5 | 2:08 |
| 31‑May‑2021 | Roland Garros | Clay | R128 | 85 | 19 | (18)Jannik Sinner [ITA] d. Herbert | 6-1 4-6 6-7(4) 7-5 6-4 | (ch) | 0.84 | 8.6% | 7.9% | 52.3% | 67.1% | 48.6% | 2/10 | 3:32 |
| 19‑Oct‑2020 | Cologne 2 | Hard | R16 | 82 | 46 | (WC)Jannik Sinner [ITA] d. (Q)Herbert | 6-3 6-1 | | 0.70 | 0.0% | 9.6% | 55.8% | 58.6% | 21.7% | 2/8 | 1:16 |
| 20‑Jan‑2020 | Australian Open | Hard | R64 | 64 | 11 | (11)David Goffin [BEL] d. Herbert | 6-1 6-4 4-6 1-6 6-3 | | 0.94 | 6.2% | 4.1% | 55.9% | 54.3% | 50.0% | 9/18 | 3:06 |
| 20‑May‑2019 | Lyon | Clay | R16 | 42 | 59 | Steve Johnson [USA] d. (7)Herbert | 7-6(6) 5-7 6-1 | | 0.81 | 7.3% | 3.7% | 61.5% | 67.2% | 54.8% | 7/11 | 2:24 |
| 11‑Feb‑2019 | Rotterdam | Hard | R32 | 36 | 7 | (1)Kei Nishikori [JPN] d. (SE)Herbert | 3-6 6-1 6-4 | | 0.57 | 5.5% | 2.7% | 55.5% | 65.6% | 49.0% | 8/11 | 2:11 |
| 14‑Jan‑2019 | Australian Open | Hard | R64 | 55 | 25 | Herbert d. (24)Hyeon Chung [KOR] | 6-2 1-6 6-2 6-4 | | 1.22 | 13.5% | 3.1% | 64.6% | 79.0% | 47.1% | 0/3 | 2:13 |
| 25‑Jun‑2018 | Antalya | Grass | QF | 75 | 30 | (2)Damir Dzumhur [BIH] d. Herbert | 6-4 6-1 | | 0.50 | 7.1% | 8.9% | 60.7% | 58.8% | 40.9% | 2/6 | 1:03 |
| 26‑Feb‑2018 | Dubai | Hard | R16 | 99 | 23 | (3)Roberto Bautista Agut [ESP] d. Herbert | 6-4 6-7(2) 6-1 | | 0.68 | 8.1% | 4.5% | 55.9% | 72.6% | 44.9% | 15/18 | 2:21 |
| 15‑Jan‑2018 | Australian Open | Hard | R128 | 74 | 60 | Denis Istomin [UZB] d. Herbert | 6-2 6-1 5-7 7-6(3) | | 0.79 | 7.7% | 5.4% | 60.0% | 69.2% | 44.2% | 7/12 | 2:58 |
| 28‑Aug‑2017 | US Open | Hard | R128 | 65 | 15 | (10)John Isner [USA] d. Herbert | 6-1 6-3 4-6 6-3 | | 0.66 | 10.1% | 7.3% | 56.9% | 72.6% | 38.3% | 4/9 | 2:23 |
| 3‑Jul‑2017 | Wimbledon | Grass | R64 | 70 | 46 | Benoit Paire [FRA] d. Herbert | 7-6(4) 6-1 6-4 | | 0.77 | 7.8% | 5.6% | 55.6% | 72.0% | 45.0% | 3/7 | 1:44 |
| 17‑Apr‑2017 | Monte Carlo Masters | Clay | R64 | 90 | 66 | (Q)Carlos Berlocq [ARG] d. (LL)Herbert | 3-6 6-2 6-1 | | 0.68 | 3.6% | 10.7% | 53.6% | 71.1% | 43.6% | 4/8 | |
| 6‑Mar‑2017 | Indian Wells Masters | Hard | R64 | 74 | 29 | (26)Fernando Verdasco [ESP] d. Herbert | 7-6(5) 6-1 | | 0.66 | 10.7% | 5.4% | 64.3% | 80.6% | 35.0% | 5/8 | 1:15 |
| 13‑Feb‑2017 | Rotterdam | Hard | SF | 109 | 11 | (3)David Goffin [BEL] d. (Q)Herbert | 6-1 6-3 | | 0.66 | 8.8% | 4.4% | 61.8% | 59.5% | 38.5% | 6/10 | 1:14 |
| 6‑Feb‑2017 | Montpellier | Hard | R16 | 96 | 14 | (2)Jo Wilfried Tsonga [FRA] d. Herbert | 6-1 6-2 | | 0.32 | 5.3% | 7.9% | 65.8% | 68.0% | 15.4% | 1/5 | 0:44 |
| 22‑Aug‑2016 | Winston-Salem | Hard | R64 | 76 | 57 | Donald Young [USA] d. Herbert | 6-4 6-1 | | 0.41 | 12.7% | 9.1% | 56.4% | 67.7% | 29.2% | 0/4 | 0:57 |
| 6‑Jun‑2016 | Stuttgart | Grass | R32 | 79 | 26 | (7)Philipp Kohlschreiber [GER] d. Herbert | 6-4 6-1 | | 0.41 | 7.1% | 7.1% | 50.0% | 57.1% | 46.4% | 3/7 | 0:55 |
| 29‑Jun‑2015 | Wimbledon | Grass | R128 | 151 | 79 | (Q)Herbert d. Hyeon Chung [KOR] | 1-6 6-2 3-6 6-2 10-8 | | 1.01 | 15.5% | 11.5% | 48.6% | 77.8% | 44.7% | 9/15 | |
| 20‑Oct‑2014 | Basel | Hard | R16 | 120 | 3 | (2)Rafael Nadal [ESP] d. (Q)Herbert | 6-1 6-1 | | 0.43 | 5.4% | 29.7% | 27.0% | 60.0% | 29.6% | 1/6 | 0:57 |
