| 11‑Jun‑2007 | Queen's Club | Grass | R32 | 69 | 24 | Marat Safin [RUS] d. Grosjean | 3-6 6-4 6-4 | | 0.86 | 1.3% | 3.8% | 58.2% | 73.9% | 54.5% | 1/4 | 1:44 |
| 10‑May‑2004 | Hamburg Masters | Clay | R64 | 10 | 21 | Marat Safin [RUS] d. (8)Grosjean | 7-6(6) 7-5 | | 0.94 | 2.4% | 1.2% | 34.9% | 89.7% | 48.1% | 5/7 | 1:58 |
| 29‑Nov‑2002 | Davis Cup WG F: FRA vs RUS | Clay | RR | 17 | 3 | Marat Safin [RUS] d. Grosjean | 6-3 6-2 7-6(11) | | | | | | | | | |
| 27‑May‑2002 | Roland Garros | Clay | QF | 10 | 2 | (2)Marat Safin [RUS] d. (10)Grosjean | 6-3 6-2 6-2 | | 0.41 | 0.0% | 0.0% | 52.3% | 52.2% | 52.4% | 7/12 | 1:43 |
| 21‑May‑2001 | Dusseldorf | Clay | RR | 10 | 2 | Grosjean d. Marat Safin [RUS] | 7-6(6) 6-3 | | | | | | | | | |
| 13‑Nov‑2000 | Paris Masters | Carpet | R16 | 21 | 2 | (2)Marat Safin [RUS] d. (16)Grosjean | 6-2 7-6(4) | | 0.82 | 6.2% | 3.1% | 49.2% | 71.9% | 39.4% | 1/4 | 1:17 |
| 28‑Aug‑2000 | US Open | Hard | R32 | 28 | 7 | (6)Marat Safin [RUS] d. Grosjean | 6-4 7-6(3) 1-6 3-6 7-6(5) | | 1.28 | 6.8% | 2.0% | 59.9% | 85.2% | 52.5% | 6/8 | 3:25 |
| 14‑Aug‑2000 | Indianapolis | Hard | QF | 25 | 7 | (3)Marat Safin [RUS] d. (12)Grosjean | 0-6 6-3 6-4 | | 0.81 | 2.6% | 3.8% | 62.8% | 65.3% | 44.8% | 4/7 | 1:21 |
| 11‑Oct‑1999 | Vienna | Hard | R16 | 30 | 35 | Grosjean d. Marat Safin [RUS] | 6-4 4-6 7-6(5) | | 1.03 | 5.2% | 7.2% | 49.5% | 75.0% | 40.8% | 1/6 | 2:02 |