| 26‑Feb‑1996 | Milan | Carpet | R32 | 78 | 12 | (7)Michael Stich [GER] d. Volkov | 6-3 6-4 | | 0.85 | 7.6% | 9.1% | 42.4% | 60.7% | 39.5% | 8/13 | 1:26 |
| 31‑Jul‑1995 | Los Angeles | Hard | QF | 33 | 9 | (2)Michael Stich [GER] d. (7)Volkov | 6-3 6-2 | | 0.69 | 1.9% | 11.3% | 39.6% | 61.9% | 53.1% | 6/9 | 1:09 |
| 20‑Feb‑1995 | Stuttgart Indoor | Carpet | QF | 40 | 9 | (5)Michael Stich [GER] d. Volkov | 6-2 7-5 | | 0.74 | 5.7% | 1.9% | 28.3% | 80.0% | 39.5% | 4/9 | 1:13 |
| 17‑Oct‑1994 | Vienna | Carpet | R32 | 41 | 3 | (2)Michael Stich [GER] d. Volkov | 6-2 6-4 | | 0.54 | 4.8% | 1.6% | 45.2% | 67.9% | 47.1% | 8/11 | 1:04 |
| 23‑Sep‑1994 | Davis Cup WG SF: GER vs RUS | Hard | RR | 42 | 2 | Volkov d. Michael Stich [GER] | 7-5 1-6 7-6(5) 6-4 | | | | | | | | | |
| 16‑May‑1994 | Dusseldorf | Clay | RR | 22 | 2 | Volkov d. Michael Stich [GER] | 6-4 7-6(5) | | | | | | | | | |
| 8‑Feb‑1993 | Milan | Carpet | R16 | 18 | 14 | (8)Michael Stich [GER] d. Volkov | 6-2 3-6 7-6(6) | | 0.68 | 4.5% | 4.5% | 64.0% | 69.0% | 52.5% | 2/4 | 2:06 |
| 18‑May‑1992 | Dusseldorf | Clay | RR | 15 | 5 | Michael Stich [GER] d. Volkov | 6-3 6-1 | | | | | | | | | |
| 24‑Jun‑1991 | Wimbledon | Grass | R16 | 25 | 7 | (6)Michael Stich [GER] d. Volkov | 4-6 6-3 7-5 1-6 7-5 | | 0.94 | 3.3% | 9.4% | 52.2% | 72.3% | 50.0% | 16/21 | 3:04 |
| 7‑Jan‑1991 | Sydney Outdoor | Hard | R32 | 24 | 38 | Michael Stich [GER] d. Volkov | 6-4 6-3 | | 0.64 | 0.0% | 3.4% | 49.2% | 79.3% | 43.3% | 6/9 | 1:09 |
| 16‑Jul‑1990 | Washington | Hard | R32 | 48 | 73 | Michael Stich [GER] d. (8)Volkov | 6-4 7-5 | | | | | | | | | |
| 16‑Oct‑1989 | Vienna | Carpet | R32 | 49 | 87 | Volkov d. Michael Stich [GER] | 7-5 6-2 | | | | | | | | | |
| 5‑Dec‑1988 | Munster CH | Carpet | F | 103 | 494 | (WC)Michael Stich [GER] d. (6)Volkov | 6-3 6-3 | | | | | | | | | |
| 21‑Nov‑1988 | Munich CH | Carpet | R16 | 140 | 546 | (1)Volkov d. (LL)Michael Stich [GER] | 6-4 6-3 | | | | | | | | | |