| 4‑Nov‑2024 | Knoxville CH | Hard | Q2 | 869 | 766 | (WC)Stefan Dostanic [USA] d. (WC)Williams | 4-6 6-2 6-1 | | 0.79 | 5.6% | 2.8% | 68.1% | 59.2% | 30.4% | 4/10 | 1:43 |
| 4‑Nov‑2024 | Knoxville CH | Hard | Q1 | 869 | 436 | (WC)Williams d. (2)Aidan Mayo [USA] | 3-6 7-6(3) 7-6(2) | | 1.09 | 2.7% | 0.9% | 61.6% | 73.9% | 55.8% | 3/6 | 3:04 |
| 28‑Oct‑2024 | Charlottesville CH | Hard | Q1 | 875 | 416 | (9)Chris Rodesch [LUX] d. Williams | 6-3 2-6 6-2 | | 0.83 | 2.5% | 7.5% | 55.0% | 70.5% | 44.4% | 5/8 | 1:47 |
| 14‑Oct‑2024 | M15 Winston-Salem NC | Hard | QF | 892 | 731 | (3)Victor Lilov [USA] d. (JE)Williams | 6-7(5) 6-3 6-4 | | | | | | | | | |
| 14‑Oct‑2024 | M15 Winston-Salem NC | Hard | R16 | 892 | 1095 | (JE)Williams d. Luca Staeheli [SUI] | 6-1 5-7 7-5 | | | | | | | | | |
| 14‑Oct‑2024 | M15 Winston-Salem NC | Hard | R32 | 892 | 1043 | (JE)Williams d. Arvid Nordquist [SWE] | 5-1 RET | | | | | | | | | |
| 16‑Sep‑2024 | Columbus CH | Hard | R32 | 885 | 116 | (1)Christopher Eubanks [USA] d. Williams | 7-5 6-3 | | 0.58 | 3.4% | 6.8% | 61.0% | 66.7% | 34.8% | 1/4 | 1:21 |
| 12‑Aug‑2024 | Cary CH | Hard | R32 | 900 | 121 | Mikhail Kukushkin [KAZ] d. (WC)Williams | 5-7 6-4 6-4 | | 0.89 | 8.6% | 1.1% | 61.3% | 68.4% | 52.8% | 2/6 | 2:35 |
| 5‑Aug‑2024 | Lincoln CH | Hard | R16 | 1017 | 295 | (Alt)Nishesh Basavareddy [USA] d. Williams | 6-3 6-0 | (ch) | 0.66 | 1.6% | 3.2% | 60.3% | 52.6% | 32.0% | 4/9 | 1:29 |
| 5‑Aug‑2024 | Lincoln CH | Hard | R32 | 1017 | 181 | Williams d. (7)Denis Yevseyev [KAZ] | 7-6(3) 7-5 | | 1.04 | 3.4% | 4.6% | 60.9% | 69.8% | 47.1% | 4/7 | 1:55 |
| 29‑Jul‑2024 | Lexington CH | Hard | Q1 | 997 | 545 | (Alt)Jack Pinnington Jones [GBR] d. (WC)Williams | 7-5 6-1 | | 0.57 | 0.0% | 5.7% | 66.0% | 51.4% | 38.9% | 1/6 | 1:16 |
| 22‑Jul‑2024 | Chicago CH | Hard | Q1 | 999 | 225 | Jacob Fearnley [GBR] d. (WC)Williams | 6-1 7-6(8) | | 0.74 | 9.7% | 1.4% | 58.3% | 66.7% | 46.7% | 4/7 | 1:37 |
| 15‑Jul‑2024 | Granby CH | Hard | Q2 | 1057 | 381 | (10)Stefan Kozlov [USA] d. Williams | 6-1 7-6(3) | | 0.61 | 10.6% | 0.0% | 56.1% | 64.9% | 51.7% | 0/2 | 1:47 |
| 15‑Jul‑2024 | Granby CH | Hard | Q1 | 1057 | 418 | Williams d. (6)Hiroki Moriya [JPN] | 6-3 6-4 | | 1.24 | 9.7% | 1.6% | 50.0% | 67.7% | 61.3% | 4/5 | 1:26 |
| 8‑Jul‑2024 | M25 Dallas TX | Hard | R16 | 1046 | 1603 | (Q)Colton Smith [USA] d. (WC)Williams | 6-2 6-3 | | | | | | | | | |
| 8‑Jul‑2024 | M25 Dallas TX | Hard | R32 | 1046 | 814 | (WC)Williams d. Shunsuke Mitsui [JPN] | 6-1 6-4 | | | | | | | | | |
| 10‑Jun‑2024 | M25 Villeneuve-Loubet+H | Clay | R32 | 1048 | 1975 | (WC)Thomas Faurel [FRA] d. (JE)Williams | 6-4 7-5 | | | | | | | | | |
| 27‑May‑2024 | Little Rock CH | Hard | R16 | 1250 | 248 | (8)Abedallah Shelbayh [JOR] d. Williams | 6-4 3-6 6-4 | | 0.97 | 4.4% | 1.1% | 67.8% | 63.9% | 44.8% | 7/12 | 2:12 |
| 27‑May‑2024 | Little Rock CH | Hard | R32 | 1250 | 467 | Williams d. (Q)Yusuke Takahashi [JPN] | 6-4 2-6 6-4 | | 1.12 | 5.2% | 2.6% | 59.7% | 73.9% | 64.5% | 1/3 | 2:14 |