29‑Oct‑2012 | Venezuela F5 | Hard | R16 | 977 | 415 | (3)Marcelo Arevalo [ESA] d. Napolitano | 7-6(2) RET | | | | | | | | | |
29‑Oct‑2012 | Venezuela F5 | Hard | R32 | 977 | | Napolitano d. (WC)Andres Gomez [ECU] | 6-2 6-3 | | | | | | | | | |
22‑Oct‑2012 | Venezuela F4 | Hard | QF | 975 | 478 | (5)Ricardo Rodriguez [VEN] d. Napolitano | 6-2 6-3 | | | | | | | | | |
22‑Oct‑2012 | Venezuela F4 | Hard | R16 | 975 | 847 | Napolitano d. Mateo Nicolas Martinez [ARG] | 3-6 7-6(4) 6-4 | | | | | | | | | |
22‑Oct‑2012 | Venezuela F4 | Hard | R32 | 975 | 1761 | Napolitano d. (Q)Antso Rakotondramanga [MAD] | 6-4 6-3 | | | | | | | | | |
24‑Sep‑2012 | Italy F28 | Hard | QF | 1914 | 362 | (4)Riccardo Bellotti [ITA] d. (WC)Napolitano | 6-3 6-4 | | | | | | | | | |
24‑Sep‑2012 | Italy F28 | Hard | R16 | 1914 | 708 | (WC)Napolitano d. (8)Giacomo Oradini [ITA] | 7-6(8) 6-1 | | | | | | | | | |
24‑Sep‑2012 | Italy F28 | Hard | R32 | 1914 | 943 | (WC)Napolitano d. Francesco Borgo [ITA] | 6-4 6-1 | | | | | | | | | |
17‑Sep‑2012 | Italy F27 | Clay | SF | 1918 | 369 | (3)Marc Giner [ESP] d. (WC)Napolitano | 6-3 6-4 | | | | | | | | | |
17‑Sep‑2012 | Italy F27 | Clay | QF | 1918 | 771 | (WC)Napolitano d. Cristian Rodriguez [COL] | 6-2 5-7 6-1 | | | | | | | | | |
17‑Sep‑2012 | Italy F27 | Clay | R16 | 1918 | 879 | (WC)Napolitano d. Romain Arneodo [FRA] | 7-5 6-4 | | | | | | | | | |
17‑Sep‑2012 | Italy F27 | Clay | R32 | 1918 | | (WC)Napolitano d. (Q)Christian Perinti [ITA] | 2-6 6-2 6-3 | | | | | | | | | |
13‑Aug‑2012 | Croatia F7 | Clay | R32 | 1904 | 953 | Nik Razborsek [SLO] d. (WC)Napolitano | 6-7(3) 6-1 6-1 | | | | | | | | | |
23‑Jul‑2012 | Italy F19 | Clay | R16 | | 497 | (7)James Lemke [AUS] d. (WC)Napolitano | 6-4 6-3 | | | | | | | | | |
23‑Jul‑2012 | Italy F19 | Clay | R32 | | 975 | (WC)Napolitano d. Matteo Volante [ITA] | 6-2 6-4 | | | | | | | | | |
9‑Jul‑2012 | San Benedetto CH | Clay | R32 | | 428 | (WC)Alessio Di Mauro [ITA] d. (WC)Napolitano | 6-2 6-4 | | 0.72 | 1.8% | 1.8% | 56.4% | 64.5% | 37.5% | 5/9 | 1:43 |
14‑May‑2012 | Italy F9 | Clay | R32 | | 265 | (5)Matteo Marrai [ITA] d. (WC)Napolitano | 6-4 7-5 | | | | | | | | | |
23‑Apr‑2012 | Napoli CH | Clay | R32 | | 428 | (Q)Roman Jebavy [CZE] d. (WC)Napolitano | 1-6 6-2 6-4 | | 1.00 | 8.6% | 0.0% | 61.4% | 55.8% | 51.9% | 3/8 | 1:38 |
9‑Apr‑2012 | Italy F4 | Clay | R32 | | 392 | Luca Vanni [ITA] d. (WC)Napolitano | 7-5 6-4 | | | | | | | | | |