| 25‑Oct‑2010 | Sao Paulo2 CH | Clay | SF | 519 | 152 | Marcos Daniel [BRA] d. (Q)Devilder | 6-4 7-5 | | 0.61 | 10.5% | 3.5% | 55.8% | 77.1% | 36.8% | 4/6 | 1:44 |
| 25‑Oct‑2010 | Sao Paulo2 CH | Clay | QF | 519 | 165 | (Q)Devilder d. Rogerio Dutra Silva [BRA] | 2-6 7-5 6-1 | | 1.14 | 13.3% | 2.4% | 59.0% | 71.4% | 50.0% | 1/4 | 1:57 |
| 25‑Oct‑2010 | Sao Paulo2 CH | Clay | R16 | 519 | 593 | (Q)Devilder d. (WC)Tiago Fernandes [BRA] | 6-3 6-4 | | 1.50 | 5.5% | 5.5% | 72.7% | 70.0% | 66.7% | 1/3 | 1:19 |
| 25‑Oct‑2010 | Sao Paulo2 CH | Clay | R32 | 519 | 126 | (Q)Devilder d. (5)Albert Ramos [ESP] | 4-6 6-1 6-4 | | 1.13 | 3.1% | 2.0% | 59.2% | 56.9% | 60.0% | 8/11 | 2:08 |
| 4‑Oct‑2010 | Palermo CH | Clay | QF | 629 | 237 | Augustin Gensse [FRA] d. (Q)Devilder | 7-6(5) 6-1 | | 0.78 | 3.4% | 0.0% | 79.3% | 47.8% | 66.7% | 0/4 | 1:45 |
| 4‑Oct‑2010 | Palermo CH | Clay | R16 | 629 | 291 | (Q)Devilder d. Nikola Mektic [CRO] | 7-6(5) 3-6 7-5 | | 0.89 | 3.3% | 3.3% | 66.1% | 63.7% | 53.7% | 6/9 | 2:49 |
| 4‑Oct‑2010 | Palermo CH | Clay | R32 | 629 | 163 | (Q)Devilder d. Simone Vagnozzi [ITA] | 6-1 5-7 7-6(7) | | 1.08 | 5.0% | 2.5% | 55.8% | 65.7% | 45.3% | 10/15 | 2:51 |
| 20‑Sep‑2010 | Bucharest | Clay | Q2 | 639 | 180 | (7)Ivan Navarro [ESP] d. Devilder | 7-5 6-7(2) 6-4 | | 0.88 | 6.5% | 1.9% | 57.0% | 70.5% | 50.0% | 2/7 | 2:31 |
| 20‑Sep‑2010 | Bucharest | Clay | Q1 | 639 | 1234 | Devilder d. (WC)Adrian Marin Dancescu [ROU] | 7-5 6-2 | | 1.33 | 8.1% | 1.6% | 54.8% | 82.4% | 46.4% | 3/4 | 1:23 |
| 13‑Sep‑2010 | Szczecin CH | Clay | R32 | 699 | 157 | Lukas Rosol [CZE] d. (Q)Devilder | 6-2 6-4 | | 0.62 | 0.0% | 15.1% | 56.6% | 53.3% | 21.7% | 1/7 | 0:54 |
| 5‑Jul‑2010 | France F11 | Clay | R32 | 675 | 1443 | (Q)Romain Arneodo [FRA] d. (8)Devilder | 7-6(5) 6-1 | | | | | | | | | |
| 14‑Jun‑2010 | France F8 | Clay | R16 | 458 | 399 | (7)Romain Jouan [FRA] d. (WC)Devilder | 7-6(6) 7-5 | | | | | | | | | |
| 14‑Jun‑2010 | France F8 | Clay | R32 | 458 | 1445 | (WC)Devilder d. (Q)Nicolas Grammare [FRA] | 6-3 6-4 | | | | | | | | | |
| 24‑May‑2010 | Roland Garros | Clay | Q3 | 477 | 146 | (29)Pablo Andujar [ESP] d. (WC)Devilder | 1-6 7-5 6-2 | | 0.79 | 3.9% | 2.0% | 71.6% | 52.1% | 51.7% | 15/20 | 2:15 |
| 24‑May‑2010 | Roland Garros | Clay | Q2 | 477 | 234 | (WC)Devilder d. Jonathan Dasnieres De Veigy [FRA] | 6-1 6-4 | | 1.46 | 1.8% | 3.6% | 69.6% | 71.8% | 64.7% | 2/2 | 1:15 |
| 24‑May‑2010 | Roland Garros | Clay | Q1 | 477 | 153 | (WC)Devilder d. (33)Igor Sijsling [NED] | 6-4 6-3 | | 1.53 | 3.4% | 1.7% | 74.6% | 72.7% | 53.3% | 1/3 | 1:15 |
| 8‑Feb‑2010 | Costa Do Sauipe | Clay | Q2 | 260 | 163 | Pablo Andujar [ESP] d. Devilder | 6-4 2-6 7-6(5) | | 0.89 | 1.0% | 3.8% | 58.1% | 67.2% | 43.2% | 5/9 | 2:44 |
| 8‑Feb‑2010 | Costa Do Sauipe | Clay | Q1 | 260 | 117 | Devilder d. (1)Pere Riba [ESP] | 6-4 6-4 | | 1.40 | 5.1% | 6.8% | 44.1% | 88.5% | 63.6% | 2/2 | 1:21 |
| 1‑Feb‑2010 | Santiago | Clay | Q2 | 259 | 185 | (8)Adrian Ungur [ROU] d. Devilder | 6-4 6-1 | | 0.80 | 4.7% | 12.5% | 39.1% | 72.0% | 33.3% | 10/15 | 1:25 |
| 1‑Feb‑2010 | Santiago | Clay | Q1 | 259 | 990 | Devilder d. Alex Theiler [CHI] | 6-1 6-3 | | 1.53 | 8.5% | 6.4% | 59.6% | 78.6% | 47.4% | 0/1 | 0:57 |
| 18‑Jan‑2010 | Australian Open | Hard | Q2 | 257 | 169 | (32)Grega Zemlja [SLO] d. Devilder | 6-3 6-3 | | 0.72 | 7.0% | 1.8% | 61.4% | 60.0% | 31.8% | 4/9 | 1:16 |
| 18‑Jan‑2010 | Australian Open | Hard | Q1 | 257 | 210 | Devilder d. Tatsuma Ito [JPN] | 6-2 6-3 | | 1.56 | 12.5% | 3.6% | 50.0% | 71.4% | 60.7% | 5/6 | 1:08 |
| 4‑Jan‑2010 | Noumea CH | Hard | R32 | 225 | 159 | (6)Flavio Cipolla [ITA] d. Devilder | 4-6 6-4 6-2 | | 0.91 | 3.1% | 4.1% | 56.7% | 58.2% | 45.2% | 3/10 | 2:22 |