| 13‑Jan‑2025 | Australian Open | Hard | QF | 1 | 8 | (1)Sinner d. (8)Alex De Minaur [AUS] | 6-3 6-2 6-1 | (ch) | 2.80 | 3.4% | 0.0% | 64.4% | 84.2% | 81.0% | 1/1 | 1:48 |
| 23‑Nov‑2024 | Davis Cup Finals SF: ITA vs AUS | Hard | RR | 1 | 9 | Sinner d. Alex De Minaur [AUS] | 6-3 6-4 | | 1.40 | 7.0% | 0.0% | 64.9% | 81.1% | 45.0% | 0/1 | 1:28 |
| 11‑Nov‑2024 | Tour Finals | Hard | RR | 1 | 9 | (1)Sinner d. (7)Alex De Minaur [AUS] | 6-3 6-4 | (ch) | 2.14 | 16.3% | 2.0% | 65.3% | 81.3% | 76.5% | 0/1 | 1:25 |
| 12‑Feb‑2024 | Rotterdam | Hard | F | 4 | 11 | (1)Sinner d. (5)Alex De Minaur [AUS] | 7-5 6-4 | (ch) | 1.03 | 4.9% | 1.2% | 55.6% | 77.8% | 38.9% | 4/6 | 2:05 |
| 26‑Nov‑2023 | Davis Cup Finals F: AUS vs ITA | Hard | RR | 4 | 12 | Sinner d. Alex De Minaur [AUS] | 6-3 6-0 | (ch) | 1.58 | 10.4% | 2.1% | 70.8% | 73.5% | 50.0% | 1/1 | |
| 30‑Oct‑2023 | Paris Masters | Hard | R16 | 4 | 13 | (13)Alex De Minaur [AUS] d. (4)Sinner | W/O | | | | | | | | | |
| 7‑Aug‑2023 | Canada Masters | Hard | F | 8 | 18 | (7)Sinner d. Alex De Minaur [AUS] | 6-4 6-1 | (ch) | 1.64 | 9.6% | 5.8% | 50.0% | 73.1% | 57.7% | 2/4 | 1:29 |
| 2‑May‑2022 | Madrid Masters | Clay | R32 | 12 | 22 | (10)Sinner d. Alex De Minaur [AUS] | 6-4 6-1 | (ch) | 1.50 | 2.0% | 6.0% | 60.0% | 70.0% | 55.0% | 2/4 | 1:14 |
| 17‑Jan‑2022 | Australian Open | Hard | R16 | 10 | 42 | (11)Sinner d. (32)Alex De Minaur [AUS] | 7-6(3) 6-3 6-4 | | 1.22 | 8.1% | 0.0% | 62.2% | 75.4% | 61.9% | 7/8 | 2:35 |
| 9‑Nov‑2020 | Sofia | Hard | QF | 44 | 25 | Sinner d. (3)Alex De Minaur [AUS] | 6-7(3) 6-4 6-1 | | 1.30 | 4.5% | 4.5% | 60.7% | 79.6% | 48.6% | 6/7 | 2:11 |
| 5‑Nov‑2019 | NextGen Finals | Hard | F | 95 | 18 | (8)Sinner d. (1)Alex De Minaur [AUS] | 4-2 4-1 4-2 | (ch) | 1.51 | 3.8% | 1.9% | 67.3% | 74.3% | 58.8% | 9/9 | 1:04 |
