| 26‑Sep‑2024 | Beijing | Hard | F | 3 | 1 | (2)Alcaraz d. (1)Jannik Sinner [ITA] | 6-7(6) 6-4 7-6(3) | (ch) | 1.16 | 4.9% | 1.6% | 60.2% | 73.0% | 55.1% | 4/6 | 3:21 |
| 27‑May‑2024 | Roland Garros | Clay | SF | 3 | 2 | (3)Alcaraz d. (2)Jannik Sinner [ITA] | 2-6 6-3 3-6 6-4 6-3 | (ch) | 0.94 | 5.1% | 4.5% | 65.6% | 66.0% | 46.3% | 4/10 | |
| 4‑Mar‑2024 | Indian Wells Masters | Hard | SF | 2 | 3 | (2)Alcaraz d. (3)Jannik Sinner [ITA] | 1-6 6-3 6-2 | (ch) | 1.09 | 0.0% | 2.8% | 65.3% | 70.2% | 52.0% | 2/4 | 2:05 |
| 27‑Sep‑2023 | Beijing | Hard | SF | 2 | 7 | (6)Jannik Sinner [ITA] d. (1)Alcaraz | 7-6(4) 6-1 | (ch) | 0.84 | 6.3% | 0.0% | 71.4% | 60.0% | 27.8% | 3/8 | 1:55 |
| 20‑Mar‑2023 | Miami Masters | Hard | SF | 1 | 11 | (10)Jannik Sinner [ITA] d. (1)Alcaraz | 6-7(4) 6-4 6-2 | (ch) | 0.81 | 4.4% | 8.0% | 54.9% | 66.1% | 41.2% | 6/12 | 3:01 |
| 6‑Mar‑2023 | Indian Wells Masters | Hard | SF | 2 | 13 | (1)Alcaraz d. (11)Jannik Sinner [ITA] | 7-6(4) 6-3 | (ch) | 1.08 | 6.9% | 1.4% | 72.2% | 73.1% | 45.0% | 1/2 | 1:52 |
| 29‑Aug‑2022 | US Open | Hard | QF | 4 | 13 | (3)Alcaraz d. (11)Jannik Sinner [ITA] | 6-3 6-7(7) 6-7(0) 7-5 6-3 | (ch) | 1.16 | 3.0% | 3.0% | 65.1% | 62.7% | 59.3% | 9/16 | 5:15 |
| 25‑Jul‑2022 | Umag | Clay | F | 5 | 10 | (2)Jannik Sinner [ITA] d. (1)Alcaraz | 6-7(5) 6-1 6-1 | (ch) | 0.73 | 2.7% | 4.0% | 66.7% | 62.0% | 56.0% | 4/9 | 2:25 |
| 27‑Jun‑2022 | Wimbledon | Grass | R16 | 7 | 13 | (10)Jannik Sinner [ITA] d. (5)Alcaraz | 6-1 6-4 6-7(8) 6-3 | (ch) | 0.79 | 7.4% | 2.5% | 66.9% | 65.4% | 57.5% | 8/12 | 3:35 |
| 1‑Nov‑2021 | Paris Masters | Hard | R32 | 35 | 9 | Alcaraz d. (8)Jannik Sinner [ITA] | 7-6(1) 7-5 | (ch) | 1.32 | 3.8% | 5.1% | 57.0% | 80.0% | 55.9% | 1/2 | 2:07 |
| 1‑Apr‑2019 | Villena CH | Clay | R64 | | 319 | (WC)Alcaraz d. (WC)Jannik Sinner [ITA] | 6-2 3-6 6-3 | (ch) | 1.17 | 0.0% | 2.5% | 68.4% | 53.7% | 60.0% | 3/8 | 1:50 |
