| 11‑Nov‑2024 | Tour Finals | Hard | RR | 2 | 3 | (2)Zverev d. (3)Carlos Alcaraz [ESP] | 7-6(5) 6-4 | (ch) | 1.33 | 12.9% | 1.4% | 78.6% | 72.7% | 66.7% | 2/2 | 1:57 |
| 27‑May‑2024 | Roland Garros | Clay | F | 4 | 3 | (3)Carlos Alcaraz [ESP] d. (4)Zverev | 6-3 2-6 5-7 6-1 6-2 | (ch) | 0.92 | 6.0% | 4.5% | 72.9% | 62.9% | 33.3% | 7/16 | |
| 4‑Mar‑2024 | Indian Wells Masters | Hard | QF | 6 | 2 | (2)Carlos Alcaraz [ESP] d. (6)Zverev | 6-3 6-1 | (ch) | 0.31 | 4.8% | 3.2% | 77.8% | 51.0% | 50.0% | 1/5 | 1:29 |
| 15‑Jan‑2024 | Australian Open | Hard | QF | 6 | 2 | (6)Zverev d. (2)Carlos Alcaraz [ESP] | 6-1 6-3 6-7(2) 6-4 | (ch) | 1.34 | 6.3% | 0.9% | 84.7% | 73.4% | 47.1% | 3/5 | 3:05 |
| 13‑Nov‑2023 | Tour Finals | Hard | RR | 7 | 2 | (7)Zverev d. (2)Carlos Alcaraz [ESP] | 6-7(3) 6-3 6-4 | (ch) | 1.17 | 16.5% | 2.1% | 77.3% | 78.7% | 50.0% | 5/6 | 2:31 |
| 28‑Aug‑2023 | US Open | Hard | QF | 12 | 1 | (1)Carlos Alcaraz [ESP] d. (12)Zverev | 6-3 6-2 6-4 | (ch) | 0.77 | 7.8% | 5.2% | 67.5% | 73.1% | 28.0% | 0/4 | 2:30 |
| 24‑Apr‑2023 | Madrid Masters | Clay | R16 | 16 | 2 | (1)Carlos Alcaraz [ESP] d. (13)Zverev | 6-1 6-2 | (ch) | 0.39 | 5.0% | 6.7% | 66.7% | 55.0% | 40.0% | 6/10 | 1:22 |
| 23‑May‑2022 | Roland Garros | Clay | QF | 3 | 6 | (3)Zverev d. (6)Carlos Alcaraz [ESP] | 6-4 6-4 4-6 7-6(7) | (ch) | 1.16 | 5.3% | 4.6% | 72.5% | 73.7% | 55.6% | 4/6 | |
| 2‑May‑2022 | Madrid Masters | Clay | F | 3 | 9 | (7)Carlos Alcaraz [ESP] d. (2)Zverev | 6-3 6-1 | (ch) | 0.31 | 6.4% | 10.6% | 66.0% | 61.3% | 25.0% | 4/8 | 1:02 |
| 25‑Oct‑2021 | Vienna | Hard | SF | 4 | 42 | (2)Zverev d. Carlos Alcaraz [ESP] | 6-3 6-3 | | 1.86 | 17.0% | 2.1% | 78.7% | 83.8% | 70.0% | 1/1 | 1:08 |
| 15‑Mar‑2021 | Acapulco | Hard | R32 | 7 | 132 | (2)Zverev d. (WC)Carlos Alcaraz [ESP] | 6-3 6-1 | | 1.70 | 22.9% | 6.3% | 60.4% | 86.2% | 42.1% | 3/4 | 1:24 |
