| 13‑Jan‑2025 | Australian Open | Hard | F | 2 | 1 | (1)Jannik Sinner [ITA] d. (2)Zverev | 6-3 7-6(4) 6-3 | (ch) | 0.66 | 12.6% | 2.1% | 68.4% | 69.2% | 50.0% | 8/10 | 2:42 |
| 28‑Aug‑2023 | US Open | Hard | QF | 12 | 1 | (1)Carlos Alcaraz [ESP] d. (12)Zverev | 6-3 6-2 6-4 | (ch) | 0.77 | 7.8% | 5.2% | 67.5% | 73.1% | 28.0% | 0/4 | 2:30 |
| 3‑Jul‑2023 | Wimbledon | Grass | R32 | 21 | 38 | Matteo Berrettini [ITA] d. (19)Zverev | 6-3 7-6(4) 7-6(5) | | 1.21 | 13.5% | 1.1% | 80.9% | 81.9% | 64.7% | 4/5 | 2:27 |
| 29‑May‑2023 | Roland Garros | Clay | SF | 27 | 4 | (4)Casper Ruud [NOR] d. (22)Zverev | 6-3 6-4 6-0 | (ch) | 0.75 | 4.3% | 2.9% | 68.1% | 55.3% | 45.5% | 4/10 | 2:09 |
| 23‑May‑2022 | Roland Garros | Clay | R64 | 3 | 36 | (3)Zverev d. Sebastian Baez [ARG] | 2-6 4-6 6-1 6-2 7-5 | (ch) | 1.10 | 7.7% | 2.6% | 68.4% | 67.9% | 46.9% | 8/13 | |
| 17‑Jan‑2022 | Australian Open | Hard | R16 | 3 | 14 | (14)Denis Shapovalov [CAN] d. (3)Zverev | 6-3 7-6(5) 6-3 | (ch) | 0.85 | 3.4% | 9.1% | 76.1% | 68.7% | 28.6% | 2/6 | 2:21 |
| 28‑Jun‑2021 | Wimbledon | Grass | R16 | 6 | 19 | (16)Felix Auger Aliassime [CAN] d. (4)Zverev | 6-4 7-6(6) 3-6 3-6 6-4 | (ch) | 0.94 | 5.4% | 11.9% | 65.5% | 79.1% | 34.5% | 8/13 | 4:02 |
| 31‑May‑2021 | Roland Garros | Clay | SF | 6 | 5 | (5)Stefanos Tsitsipas [GRE] d. (6)Zverev | 6-3 6-3 4-6 4-6 6-3 | (ch) | 0.89 | 7.7% | 4.9% | 69.7% | 74.7% | 39.5% | 9/14 | 3:37 |
| 31‑May‑2021 | Roland Garros | Clay | R128 | 6 | 152 | (6)Zverev d. (Q)Oscar Otte [GER] | 3-6 3-6 6-2 6-2 6-0 | | 1.43 | 8.3% | 7.4% | 57.4% | 74.2% | 58.7% | 2/6 | 2:49 |
| 28‑Sep‑2020 | Roland Garros | Clay | R16 | 7 | 75 | Jannik Sinner [ITA] d. (6)Zverev | 6-3 6-3 4-6 6-3 | (ch) | 0.94 | 2.8% | 3.7% | 65.7% | 71.8% | 40.5% | 1/6 | 3:01 |
| 31‑Aug‑2020 | US Open | Hard | SF | 7 | 27 | (5)Zverev d. (20)Pablo Carreno Busta [ESP] | 3-6 2-6 6-3 6-4 6-3 | (ch) | 1.12 | 17.4% | 5.8% | 62.3% | 77.9% | 36.5% | 9/16 | 3:23 |
| 27‑May‑2019 | Roland Garros | Clay | QF | 5 | 1 | (1)Novak Djokovic [SRB] d. (5)Zverev | 7-5 6-2 6-2 | | 0.69 | 11.9% | 9.5% | 69.0% | 65.5% | 34.6% | 5/11 | 2:09 |
| 14‑Jan‑2019 | Australian Open | Hard | R16 | 4 | 17 | (16)Milos Raonic [CAN] d. (4)Zverev | 6-1 6-1 7-6(5) | (ch) | 0.63 | 6.7% | 11.1% | 62.2% | 67.9% | 35.3% | 14/20 | 1:59 |
| 28‑May‑2018 | Roland Garros | Clay | QF | 3 | 8 | (7)Dominic Thiem [AUT] d. (2)Zverev | 6-4 6-2 6-1 | (ch) | 0.51 | 2.2% | 4.5% | 71.9% | 53.1% | 44.0% | 6/12 | 1:50 |
| 6‑Apr‑2018 | Davis Cup WG QF: ESP vs GER | Clay | RR | 4 | 1 | Rafael Nadal [ESP] d. Zverev | 6-1 6-4 6-4 | (ch) | 0.68 | 6.2% | 4.9% | 65.4% | 56.6% | 42.9% | 2/8 | 2:16 |
| 29‑Aug‑2016 | US Open | Hard | R64 | 28 | 64 | Daniel Evans [GBR] d. (27)Zverev | 6-4 6-4 5-7 6-2 | | 0.84 | 4.3% | 6.4% | 62.9% | 65.9% | 46.2% | 8/14 | 3:09 |
| 27‑Jun‑2016 | Wimbledon | Grass | R32 | 28 | 9 | (10)Tomas Berdych [CZE] d. (24)Zverev | 6-3 6-4 4-6 6-1 | | 0.67 | 6.0% | 5.2% | 64.2% | 61.6% | 41.7% | 4/10 | 2:39 |
| 4‑Mar‑2016 | Davis Cup WG R1: GER vs CZE | Hard | RR | 58 | 50 | Lukas Rosol [CZE] d. Zverev | 6-2 6-3 6-1 | | 0.52 | 7.2% | 4.8% | 66.3% | 49.1% | 60.7% | 6/12 | 1:38 |
| 18‑Jan‑2016 | Australian Open | Hard | R128 | 83 | 2 | (2)Andy Murray [GBR] d. Zverev | 6-1 6-2 6-3 | | 0.57 | 5.5% | 7.7% | 62.6% | 63.2% | 32.4% | 7/13 | 2:07 |
